A rise in oxidation number identifies oxidation; a fall identifies reduction. The oxidised reactant is the reducing agent, and the reduced reactant is the oxidising agent.
(a) Hydroquinone, (mathrm{C_6H_6O_2}), is oxidised to quinone, (mathrm{C_6H_4O_2}). Silver(I) in AgBr is reduced to Ag. Therefore hydroquinone is the reducing agent and AgBr is the oxidising agent.
(b) Carbon in HCHO changes from 0 to +2 in (mathrm{HCOO^-}), so HCHO is oxidised and is the reducing agent. Ag(I) in (mathrm{[Ag(NH_3)_2]^+}) changes to Ag(0), so the silver complex is reduced and is the oxidising agent.
(c) Carbon in HCHO changes from 0 to +2 in (mathrm{HCOO^-}), so HCHO is oxidised and is the reducing agent. Cu(II) changes to Cu(I) in (mathrm{Cu_2O}), so (mathrm{Cu^{2+}}) is reduced and is the oxidising agent.
(d) Nitrogen changes from -2 in (mathrm{N_2H_4}) to 0 in (mathrm{N_2}), so hydrazine is oxidised and is the reducing agent. Oxygen changes from -1 in (mathrm{H_2O_2}) to -2 in water, so hydrogen peroxide is reduced and is the oxidising agent.
(e) Pb(0) changes to Pb(II) in (mathrm{PbSO_4}), so Pb is oxidised and is the reducing agent. Pb(IV) in (mathrm{PbO_2}) changes to Pb(II), so (mathrm{PbO_2}) is reduced and is the oxidising agent.
Final answers by part(a) Oxidised: hydroquinone; reduced: AgBr; OA: AgBr; RA: hydroquinone.
(b) Oxidised: HCHO; reduced: Ag(I); OA: silver-ammonia complex; RA: HCHO.
(c) Oxidised: HCHO; reduced: Cu(II); OA: (mathrm{Cu^{2+}}); RA: HCHO.
(d) Oxidised: (mathrm{N_2H_4}); reduced: (mathrm{H_2O_2}); OA: (mathrm{H_2O_2}); RA: (mathrm{N_2H_4}).
(e) Oxidised: Pb; reduced: (mathrm{PbO_2}); OA: (mathrm{PbO_2}); RA: Pb.