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Solution to Question 831
Complete workingApply ozone cleavage to the two Kekulé arrangements of o-xylene. Each arrangement gives a different set of dialdehyde/dicarbonyl fragments.
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Apply ozone cleavage to the two Kekulé arrangements of o-xylene. Each arrangement gives a different set of dialdehyde/dicarbonyl fragments.
Explain inductive and electromeric effects, then account for the acidity orders Cl₃CCOOH>Cl₂CHCOOH>ClCH₂COOH and CH₃CH₂COOH>(CH₃)₂CHCOOH>(CH₃)₃CCOOH.
The inductive effect is permanent sigma-bond polarisation; the electromeric effect is temporary complete transfer of pi electrons during attack. Compare substituent electron withdrawal/donation.
More Cl atoms strengthen the −I effect and stabilise carboxylate, increasing acidity. Increasing alkyl substitution strengthens +I donation and destabilises carboxylate, decreasing acidity in the stated order.
Consider the reactions:
Compare which oxidant is reduced by each substrate. Both Ag⁺ and Cu²⁺ oxidise H₃PO₂, but only Ag⁺ oxidises benzaldehyde under the stated test conditions.
Kp = 0.04 atm at 899 K for the equilibrium shown below. Determine the equilibrium concentration of C2H6 when it is placed in a flask at 4.0 atm pressure and allowed to come to equilibrium? C2H6 (g) C2H4 (g) + H2 (g)
Let x atm C₂H₆ dissociate. Then Kp=x²/(4−x)=0.04; the physical root is x≈0.38 atm.
p(C₂H₆)≈3.62 atm.
For 2A+B→C, ΔH=400 kJ mol⁻¹ and ΔS=0.200 kJ K⁻¹ mol⁻¹. Above what temperature is the reaction spontaneous?
Set ΔG=ΔH−TΔS equal to zero at the boundary. With both ΔH and ΔS positive, spontaneity occurs above this temperature.
T>2000 K.
Define electronegativity and distinguish it from electron-gain enthalpy.
Electronegativity is a relative, dimensionless tendency of a bonded atom to attract shared electrons. Electron-gain enthalpy is the measurable enthalpy change when an isolated gaseous atom gains an electron.
Why is Na lower than Mg in first ionisation enthalpy but higher in second ionisation enthalpy?
Na first loses its single 3s electron easily. Na⁺ then has a noble-gas shell, so its second electron would be removed from the core. Mg⁺ still has one 3s electron for its second ionisation.
IE₁(Na)IE₂(Mg).
Calculate the wavenumber of the longest-wavelength line in hydrogen's Balmer series.
The longest Balmer wavelength is the smallest Balmer energy gap, n=3 to n=2.
Water contains 15 ppm by mass of chloroform, CHCl₃. Express this as: (i) percentage by mass(ii) molality of chloroform.
Use a 10⁶ g sample of solution. It contains \(15\,\mathrm{g}\) chloroform and approximately \(999985\,\mathrm{g}\) water.
A soap film supports a 1.5×10⁻² N slider \(30\,\mathrm{cm}\) long. Find the surface tension.
Principle and reasoning. Work from the governing physical relation and apply it to every stated part.
The film has two surfaces, each exerting force Sl along the slider.